The Pokémon TCG: Celebrations Special Collection—Pikachu V-UNION includes:

- 4 foil promo cards that make up a single Pikachu V-UNION
- 1 oversize card featuring Pikachu V-UNION
- 1 helpful Supporter card featuring Professor Burnet
- 4 Pokémon TCG: Celebrations 4-card boosters
- 2 additional Pokémon TCG boosters, each containing 10 cards and 1 basic Energy
- A code card for the Pokémon Trading Card Game Online